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... ATP + ADP Mg++ Aldolase + Dihydroxyacetone phosphate (DHAP) Glyceraldehyde-3-phosphate (GAP) Fructose -1,6-bisphosphate (FBP) Aldol cleavage (retro aldol condensation ...

Robinson Annulation Another example: Michael addition followed by an aldol condensation. C. Gilman Reagents Gilman reagents undergo conjugate addition to ...

Ch. 18 Lect. 2 Complex Carbonyl Reactions Aldol Condensation Two aldehyde molecules can react to form an a,b-unsaturated aldehyde product This reaction allow C—C ...

... glycolysis + ATP + ADP Mg++ + Dihydroxyacetone phosphate (DHAP) Glyceraldehyde-3-phosphate (GAP) Fructose -1,6-bisphosphate (FBP) Aldol cleavage (retro aldol condensation ...

Know the mechanism of the aldol condensation/dehydration sequence. Be able to draw the resultant chalcone given a benzaldehyde and ...

... with the conversion of acetate to acetyl CoA followed by Claisen condensation to yield acetoacetyl CoA Catalyzed by acetoacetyl-CoA acetyltransferase * Aldol Condensation ...

... Formation of a Hexose Dihydroxyacetone phosphate and glyceraldehyde 3-phosphate combine to give the diphosphate of fructose The reaction is an enzymic aldol condensation ...

... with the conversion of acetate to acetyl CoA followed by Claisen condensation to yield acetoacetyl CoA Catalyzed by acetoacetyl-CoA acetyltransferase * Aldol Condensation ...

A new C-C bond is formed 21.2 Intramolecular Claisen Condensation: The Dieckmann Reaction 21.3 Mixed Claisen Condensations As with mixed aldol condensations, mixed ...

Carbon-Carbon Bond Forming Reactions I. Substitution Reaction II. Addition Reaction Enantio-selective aldol condensation iii) Chiral auxiliary D.A. Evans Reliable ...

... Synthesis: Retrosyntheic Analysis Recognition pattern Analysis Synthesis: Retrosyntheic Analysis Example Mixed aldol Benzaldehyde No alpha hydrogens Claisen Condensation ...

CARBONYL CONDENSATION REACTIONS CARBONYL CONDENSATION REACTIONS Aldol Reaction Dehydration of Aldol Products Intramolecular Aldol Reaction Claisen Condensation ...

Carbanions as the nucleophiles in nucleophilic addition to aldehydes and ketones: a) aldol condensation “crossed” aldol condensation b) aldol related ...

Experiment 22: THE SOLVENTLESS ALDOL-TYPE CONDENSATION Objectives: To synthesize an a,b unsaturated ketone from an aldehyde and a ketone using solvent-free conditions.

... acetone The Reversibility of Aldol Additions Aldol addition products undergo retro-aldol reactions in the presence of strong base Acid-Catalyzed Aldol Condensation ...

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